California Department of Fish and Wildlife, Office of Spill Prevention and Response 20220222 vector digital data https://wildlife.ca.gov/Data/BIOS https://filelib.wildlife.ca.gov/Public/BDB/GIS/BIOS/Public_Datasets/700_799/ds714.zip Polycyclic aromatic hydrocarbons (PAHs) are a class of organic compounds found in the environment associated with natural and anthropogenic activities such as the refinement and use of petroleum hydrocarbons as fuels and lubricants. When an oil spill occurs in California, an understanding of pre-spill or ambient levels of PAHs is crucial for understanding the existing environmental conditions before a release occurs. Anthropogenic (e.g., vehicle and boat exhaust, wood burning, industrial activities, oil spills) and natural releases (i.e., forest fires, oil seeps) of PAHs are common sources of these compounds in the environment. Ambient or pre-spill data are critical to identify the need for, and scope of, subsequent environmental sampling, and injury assessment. The Office of Spill Prevention and Response (OSPR) in collaboration with industry representatives (Chevron) and other state and federal trustee agencies (Department of Fish and Game, U.S. Fish and Wildlife Service, Bureau of Land Management, National Oceanic and Atmospheric Administration) have collected environmental samples (e.g., water, sediment, and tissue) for polycyclic aromatic hydrocarbon (PAH) chemical analysis from coastal and inland locations. In addition, plans to collect PAH monitoring data in California for the purpose of being prepared for oil spills and assessing natural resource injuries have been developed. Between 2011 and 2019, Chevron and the Trustees collected samples in Eureka/Humboldt Bay, Richmond, El Segundo, and San Diego, CA for PAH analysis to begin assessing ambient conditions. Chevron and the Trustees have the common understanding that the interpretation of statistical comparisons of these data to spill data (in the event one occurs) must take into consideration the sample size and geographic coverage of the available PAH monitoring data. From 2017 to present, CDFW-OSPR has collected samples in the Feather River Canyon, along the Upper Sacramento River, in Elkhorn Slough and Monterey Bay. These data are collected for the purpose of being prepared for oil spills and assessing natural resource injuries. Concentrations of polycyclic aromatic hydrocarbons (PAHs) in surface water, sediment, and tissue (i.e., mussels, oysters, crayfish) are proposed in coastal and inland areas subject to potential oil spills due to refinery and transport activities. Additional information on the different types of Polycyclic aromatic hydrocarbon samples can be found at the links below: Humbolt Bay: Tissue: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=55285 Sediment: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=55284 Surface Water: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=55282 Santa Monica: Sediment: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=57530 Water: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=57531 Mussel tissue: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=57529 San Diego: Sediments (1): https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=64006 Sediments (2): https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=64008 Mussel Tissue: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=64005 Surface Water: https://nrm.dfg.ca.gov/FileHandler.ashx?DocumentID=64004 In work As needed -124.246073 -116.929862 41.246904 32.728276 ISO 19115 Topic Category PAH, OSPR, Polycyclic Aromatic Hydrocarbon, EDCP, Ephemeral data collection, chemistry, ambient, sampling, tissue, water, sediment, hydrocarbons None Santa Monica Bay, Eureka, Humboldt Bay, El Segundo, San Diego, Richmond, Monterey Bay, Elkhorn Slough, Feather River, Sacramento River, Truckee River, Donner Lake, California None License: This work is licensed under Creative Commons Attribution 4.0 International License ( https://creativecommons.org/licenses/by/4.0/). Using the citation standards recommended for BIOS datasets ( https://www.wildlife.ca.gov/Data/BIOS/Citing-BIOS ) satisfies the attribution requirements of this license.Disclaimer: The State makes no claims, promises, or guarantees about the accuracy, completeness, reliability, or adequacy of these data and expressly disclaims liability for errors and omissions in these data. No warranty of any kind, implied, expressed, or statutory, including but not limited to the warranties of non-infringement of third party rights, title, merchantability, fitness for a particular purpose, and freedom from computer virus, is given with respect to these data. California Department of Fish and Wildlife, Office of Spill Prevention and Response April DaSilva Staff Toxicologist (916) 216-6299 April.DaSilva@wildlife.ca.gov California Department of Fish and Wildlife, Office of Spill Prevention and Response Michael J. Anderson, Ph.D. Environmental Program Manager physical

1010 Riverside Pkwy

West Sacramento CA 95605 US 916-826-1136 916-371-8950 Michael.Anderson@wildlife.ca.gov California Department of Fish and Wildlife, Office of Spill Prevention and Response April DaSilva Staff Toxicologist (916) 216-6299 April.DaSilva@wildlife.ca.gov California Department of Fish and Wildlife Version 6.2 (Build 9200) ; Esri ArcGIS 10.5.1.7333 Obtained excel spreadsheets containing data. The spreadsheets were consolidated and metadata created. The consolidated spreadsheet was imported into ArcPro 2.7 and lat/lon data were plotted. The plotted spreadsheet was exported to file geodatabase feature class and reprojected to Teale Alber's NAD83. 20210511 California Department of Fish and Wildlife Joel Boros BIOS Librarian (Lead) Vector Entity point 317 NAD 1983 California Teale Albers 34.0 40.5 -120.0 0.0 0.0 -4000000.0 coordinate pair 0.0001 0.0001 meter D North American 1983 GRS 1980 6378137.0 298.257222101 ds714 OBJECTID Internal feature number. Esri Sequential unique whole numbers that are automatically generated. Region General area in which data are located. California Department of Fish and Game Location Location. California Department of Fish and Game, Office of Spill Prevention and Response Sample_Typ Type of Sample. California Department of Fish and Game, Office of Spill Prevention and Response Medium Type of medium. California Department of Fish and Game, Office of Spill Prevention and Response Sample_ID Sample Identification Number. California Department of Fish and Game, Office of Spill Prevention and Response Date_Col Date Collected. California Department of Fish and Game, Office of Spill Prevention and Response Time_Col Time Collected (24hr). California Department of Fish and Game, Office of Spill Prevention and Response Date_Rec Date Received California Department of Fish and Game, Office of Spill Prevention and Response Date_Extrc Date Extracted. California Department of Fish and Game, Office of Spill Prevention and Response Date_Analy Date Analyzed. California Department of Fish and Game, Office of Spill Prevention and Response Mass__Vol_Extrc Sample Mass Extracted (wet, g); Sample Volume Extracted (wet, mL). California Department of Fish and Game, Office of Spill Prevention and Response Dry_Samp_Mass Dry Sample Mass (g). California Department of Fish and Game, Office of Spill Prevention and Response Moisture Percent Moisture. California Department of Fish and Game, Office of Spill Prevention and Response Measure Measurement. California Department of Fish and Game, Office of Spill Prevention and Response RL Reporting Limit ng/g (ppb); µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Naph Naphthalene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F2_MeNaph 2-Methylnaphthalene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F1_MeNaph 1-Methylnaphthalene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F2_6_MeNaph 2,6-Dimethylnaphthalene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F2_3_5_MeNaph 2,3,5-Trimethylnaphthalene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_Naph Naphthalenes, C1- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C2_Naph Naphthalenes, C2- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C3_Naph Naphthalenes, C3- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C4_Naph Naphthalenes, C4- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Biphenyl Biphenyl ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Acy Acenaphthylene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Ace Acenaphthene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Fluor Fluorene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response F1_MeFluor 1-Methylfluorene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_Fluor Fluorenes, C1- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C2_Fluor Fluorenes, C2- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C3_Fluor Fluorenes, C3- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response DBT Dibenzothiophene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response F4_MeDBT 4-Methyldibenzothiophene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_DBT Dibenzothiophenes, C1- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C2_DBT Dibenzothiophenes, C2- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C3_DBT Dibenzothiophenes, C3- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Phen Phenanthrene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response F1_MePhen 1-Methylphenanthrene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F3_6_DiMePh 3,6-Dimethylphenanthrene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_Phen_Ant C1- Phenanthrenes/Anthracenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C2_Phen_Ant C2-Phenanthrenes/Anthracenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C3_Phen_Ant C3-Phenanthrenes/Anthracenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Ant Anthracene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Fluorant Fluoranthene; ng/g(ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F2_MeFluorant 2- Methylfluoranthene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_Fluorant_Pyr C1- Fluoranthenes/Pyrenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Pyr Pyrene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response B_a_Ant Benz(a)anthracene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Chry Chrysene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C1_Chry Chrysenes, C1- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C2_Chry Chrysenes, C2- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response C3_Chry Chrysenes, C3- ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response B_b_Fluorant Benzo(b)fluoranthene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response B_k_Fluorant Benzo(k)fluoranthene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response B_e_Pyr Benzo(e)pyrene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response B_a_Pyr Benzo(a)pyrene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Pery Perylene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response IDP Indeno(1,2,3-c,d)pyrene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response D_a_h_Ant Dibenz(a,h)anthracene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response B_g_h_i_Pe Benzo(g,h,i)perylene ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Sum_PAH Sum PAH concentration ng/g(ppb) Dry Weight. California Department of Fish and Game, Office of Spill Prevention and Response Per_Recov Percent. California Department of Fish and Game, Office of Spill Prevention and Response Naph_d8 Naphthalene-d8(Surrogate)(Percent). California Department of Fish and Game, Office of Spill Prevention and Response Biphen_d10 Biphenyl-D10(Surrogate)(Percent). California Department of Fish and Game, Office of Spill Prevention and Response Ace_d10 Acenaphthene-d10(Surrogate)(Percent). California Department of Fish and Game, Office of Spill Prevention and Response Phen_d10 Phenanthrene-d10(Surrogate); Percent. California Department of Fish and Game, Office of Spill Prevention and Response Pyr_d10 Pyrene-d10(Surrogate)(Percent). California Department of Fish and Game, Office of Spill Prevention and Response B_a_Ant_d12 Benz(a)anthracene-D12(Surrogate); Percent. California Department of Fish and Game, Office of Spill Prevention and Response Pery_d12 Perylene-d12(Surrogate); Percent. California Department of Fish and Game, Office of Spill Prevention and Response B_g_h_i_Pery_d12 Benzo(g,h,i)perylene-D12(Surrogate); Percent. California Department of Fish and Game, Office of Spill Prevention and Response Avg_Recov Average. California Department of Fish and Game, Office of Spill Prevention and Response C4_Phen_Ant C4- Phenanthrenes/Anthracenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C4_Chry C4-Chrysenes; ng/g (ppb) Dry Weight; µg/L (ppb) California Department of Fish and Game, Office of Spill Prevention and Response Chry_d12 Chrysene-d12(Surrogate); Percent California Department of Fish and Game, Office of Spill Prevention and Response B_b_ThPh Benzo(b)thiophene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_B_b_ThPh C1-Benzo(b)thiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C2_B_b_ThPh C2-Benzo(b)thiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C3_B_b_ThPh C3-Benzo(b)thiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response cis_Dec cis-Decalin; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response trans_Dec trans-Decalin; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_Dec C1-Decalins; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C2_Dec C2-Decalins; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C3_Dec C3-Decalins; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C4_Dec C4-Decalins; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Ret Retene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response B_b_NTP Benzo(b)naphtho(2,1-d)thiophene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Dec Decalin; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_B_b_NTP C1-benzo(b)naphthothiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C2_B_b_NTP C2-benzo(b)naphthothiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C3_B_b_NTP C3-benzo(b)naphthothiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response DBF Dibenzofuran; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response B_a_Pyr_d12 Benzo(a)pyrene-d12(Surrogate); Percent. California Department of Fish and Game, Office of Spill Prevention and Response F1_MeDBT 1-Methyldibenzothiophene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F2_MeDBT 2-Methyldibenzothiophene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C4_DBT C4-Dibenzothiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F2_MePhen 2-Methylphenanthrene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F3_MePhen 3-Methylphenanthrene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F9_MePhen 9-Methylphenanthrene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response F2_MeAnt 2-methylanthracene; ng/g(ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C2_Fluorant_Pyr C2- Fluoranthenes/Pyrenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C3_Fluorant_Pyr C3- Fluoranthenes/Pyrenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C4_Fluorant_Pyr C4- Fluoranthenes/Pyrenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C1_D_a_h_Ant C1-Dibenz(a,h)anthracene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C2_D_a_h_Ant C2-Dibenz(a,h)anthracene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C3_D_a_h_Ant C3-Dibenz(a,h)anthracene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C4_B_b_NTP C4-benzo(b)naphthothiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response B_a_Fluorant Benzo(a)fluoranthene; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response C4_B_b_ThPh C4-Benzo(b)thiophenes; ng/g (ppb) Dry Weight; µg/L (ppb). California Department of Fish and Game, Office of Spill Prevention and Response Lab_Num CDFW Water Pollution Control Lab Number; Battelle Lab Number; ALS Environmental Lab Number. California Department of Fish and Game, Office of Spill Prevention and Response Latitude Latitude coordinate in decimal degrees. California Department of Fish and Game, Office of Spill Prevention and Response Longitude Longitude coordinate in decimal degrees. California Department of Fish and Game, Office of Spill Prevention and Response Shape Feature geometry. Esri Coordinates defining the features. Fluor_d10 Fluorene-d10(Surrogate); Percent California Department of Fish and Game, Office of Spill Prevention and Response Fluorant_d10 Fluoranthene-d10(Surrogate); Percent California Department of Fish and Game, Office of Spill Prevention and Response Terph_d14 Terphenyl-d14(Surrogate); Percent California Department of Fish and Game, Office of Spill Prevention and Response 20220222 California Department of Fish and Wildlife, Office of Spill Prevention and Response April DaSilva Staff Toxicologist (916) 216-6299 April.DaSilva@wildlife.ca.gov FGDC Content Standard for Digital Geospatial Metadata FGDC-STD-001-1998 local time